Car Converters Views
These three reactions occur most efficiently when the catalytic converter receives exhaust from an engine running slightly above the stoichiometric point. This point is between 14.6 and 14.8 parts air to 1 part fuel, by weight, for gasoline. The ratio for Autogas (or liquefied petroleum gas (LPG)), natural gas and ethanol fuels is slightly different, requiring modified fuel system settings when using those fuels. Generally, engines fitted with 3-way catalytic converters are equipped with a computerized closed-loop feedback fuel injection system using one or more oxygen sensors, though early in the deployment of three-way converters, carburetors equipped for feedback mixture control were used.
For compression-ignition (i.e., diesel engines), the most-commonly-used catalytic converter is the diesel oxidation catalyst. This catalyst uses O2 (oxygen) in the exhaust gas stream to convert CO (carbon monoxide) to CO2 (carbon dioxide) and HC (hydrocarbons) to H2O (water) and CO2. These converters often operate at 90 percent efficiency, virtually eliminating diesel odor and helping to reduce visible particulates (soot). But they cannot reduce NOx because chemical reactions always occur in the simplest possible way, and the existing O2 in the exhaust gas stream would react first.
Diesel-engine exhaust contains relatively high levels of particulate matter (soot), consisting in large part of elemental carbon. Catalytic converters cannot clean up elemental carbon, though they do remove up to 90 percent of the soluble organic fraction[citation needed], so particulates are cleaned up by a soot trap or diesel particulate filter (DPF). In the U.S., all on-road heavy-duty vehicles powered by diesel and built after January 1, 2007, must be equipped with a catalytic converter and a diesel particulate filter.[7]
Because of the external location and the use of valuable precious metals including platinum, palladium, and rhodium, converters are a target for thieves. The problem is especially common among late-model Toyota trucks and SUVs, because of their high ground clearance and easily removed bolt-on catalytic converters. Welded-in converters are also at risk of theft from SUVs and trucks, as they can be easily removed.[18][19] Theft removal of the converter can often inadvertently damage the car's wiring or fuel line resulting in dangerous consequences. Rises in metal costs in the U.S. during recent years have led to a large increase in theft incidents of the converter,[20] which can then cost as much as $1,000 to replace.[21]